ACRYLIC ACID, [WASTE]
UN/NA Number - The United Nations-North America number (also called UN number or DOT number). 4-digit number identifying an individual chemical or group of chemicals with similar characteristics. Required on shipping papers; often shown on placards or labels. This numbering system was developed by the U.S. Department of Transportation, and then became the UN standard system for classifying hazardous materials.
DOT Hazard Label - U.S. Department of Transportation hazard warning label for the chemical (such as flammable liquid or corrosive). This label must be displayed on shipped packages, railroad tank cars, and tank trucks according to specifications described in 49 CFR 172.
CHRIS Code - 3-letter code used by the U.S. Coast Guard to identify individual chemicals included in its CHRIS (Chemical Hazards Response Information System) manual.
NFPA 704 - Text description of the diamond-shaped placard, which contains codes indicating the level of the chemical's health, flammability, and instability hazards, along with special hazards such as water- and air-reactivity. See a guide to the NFPA diamond.
General Description - Brief description of the chemical's general appearance, behavior, and hazardousness.
List of data sources.
|CAS Number||UN/NA Number||DOT Hazard Label||CHRIS Code|
|Health||3||Can cause serious or permanent injury.|
|Flammability||2||Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur.|
|Instability||2||Readily undergoes violent chemical changes at elevated temperatures and pressures.|
Air & Water Reactions - Special alerts if the chemical reacts with air, water, or moisture.
Fire Hazard - Description of the chemical's fire hazards (such as flammability, explosion risk, or byproducts that may evolve if the chemical is burned).
Health Hazard - Description of the chemical's health hazards (such as toxicity, flammability, or corrosivity).
Reactivity Profile - Description of the chemical's potential reactivity with other chemicals, air, and water. Also includes any other intrinsic reactive hazards (such as polymerizable or peroxidizable).
Reactive Groups - List of reactive groups that the chemical is assigned to, based on its known chemistry. Reactive groups are categories of chemicals that react in similar ways because their chemical structures are similar. Reactive groups are used to predict reactivity when you add a chemical to MyChemicals. Read more about reactive groups.
Potentially Incompatible Absorbents - Absorbents are products that can be used to soak up liquids from spills. However, some absorbents can react with particular chemicals (that is, they are incompatible), so caution should be used in selecting the correct absorbent for your situation. This section provides a list of potentially incompatible absorbents that have been known to react with liquids assigned to one or more of the reactive groups listed on this datasheet. Read more about absorbents, including situations to watch out for.
List of data sources.
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. (ERG, 2012)
Symptoms: Irritation eyes, skin, respiratory system; eye, skin burns; skin sensitization
Target Organs: Eyes, skin, respiratory system (NIOSH, 2003)
Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below. More info about absorbents, including situations to watch out for...
- Cellulose-Based Absorbents
- Mineral-Based & Clay-Based Absorbents
Firefighting - Response recommendations if the chemical is on fire (or near a fire).
Non-Fire Response - Response recommendations if the chemical isn't on fire (or near a fire).
Protective Clothing - Recommendations for protective gear.
Dupont Tychem® Suit Fabrics - A table of normalized breakthrough times for DuPont Tychem suit fabrics for the chemical, if available.
First Aid - Recommended first aid treatment for people exposed to the chemical.
List of data sources.
As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions.
SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above.
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2012)
Some of these materials may react violently with water.
SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam.
LARGE FIRE: Water spray, fog or alcohol-resistant foam. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material. Do not get water inside containers.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2012)
Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb with earth, sand or other non-combustible material and transfer to containers (except for Hydrazine). Use clean non-sparking tools to collect absorbed material.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor; but may not prevent ignition in closed spaces. (ERG, 2012)
Eyes: Wear appropriate eye protection to prevent eye contact.
Wash skin: The worker should immediately wash the skin when it becomes contaminated.
Remove: Work clothing that becomes wet or significantly contaminated should be removed and replaced.
Change: No recommendation is made specifying the need for the worker to change clothing after the work shift.
Provide: Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substance; this is irrespective of the recommendation involving the wearing of eye protection. Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] (NIOSH, 2003)
|QC = Tychem QC|
|SL = Tychem SL|
|TF = Tychem F|
|TP = Tychem ThermoPro|
|C3 = Tychem CPF 3|
|BR = Tychem BR|
|LV = Tychem LV|
|RC = Tychem Responder® CSM|
|TK = Tychem TK|
|RF = Tychem Reflector®|
"imm." indicates immediate; having a normalized breakthrough time of 10 minutes or less.
A blank cell indicates the fabric has not been tested. The fabric may or may not offer barrier.
Special Warnings from DuPont
- Serged and bound seams are degraded by some hazardous liquid chemicals, such as strong acids, and should not be worn when these chemicals are present.
CAUTION: This information is based upon technical data that
DuPont believes to be reliable. It is subject to revision as
additional knowledge and experience are gained. DuPont makes no
guarantee of results and assumes no obligation or liability...
... in connection with this information. It is the user's responsibility to determine the level of toxicity and the proper personal protective equipment needed. The information set forth herein reflects laboratory performance of fabrics, not complete garments, under controlled conditions. It is intended for informational use by persons having technical skill for evaluation under their specific end-use conditions, at their own discretion and risk. Anyone intending to use this information should first verify that the garment selected is suitable for the intended use. In many cases, seams and closures have shorter breakthrough times and higher permeation rates than the fabric. Please contact DuPont for specific data. If fabric becomes torn, abraded or punctured, or if seams or closures fail, or if attached gloves, visors, etc. are damaged, end user should discontinue use of garment to avoid potential exposure to chemical. Since conditions of use are outside our control, we make no warranties, express or implied, including, without limitation, no warranties of merchantability or fitness for a particular use and assume no liability in connection with any use of this information. This information is not intended as a license to operate under or a recommendation to infringe any patent or technical information of DuPont or others covering any material or its use.
Skin: If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly.
Breathing: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscitation. Keep the affected person warm and at rest. Get medical attention as soon as possible.
Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 2003)
See also the Levels of Concern guide for information on AEGLs, ERPGs, PACs, and IDLH values.
List of data sources.
AEGLs (Acute Exposure Guideline Levels)
|10 minutes||1.5 ppm||68 ppm||480 ppm|
|30 minutes||1.5 ppm||68 ppm||260 ppm|
|60 minutes||1.5 ppm||46 ppm||180 ppm|
|4 hours||1.5 ppm||21 ppm||85 ppm|
|8 hours||1.5 ppm||14 ppm||58 ppm|
ERPGs (Emergency Response Planning Guidelines)
|Acrylic Acid (79-10-7)||1 ppm||50 ppm||250 ppm|
PACs (Protective Action Criteria)
|Acrylic acid (79-10-7)||1.5 ppm||46 ppm||180 ppm||LEL = 24000 ppm|
|Regulatory Name||CAS Number/
313 Category Code
|CERCLA RQ||EPCRA 313
(EPA List of Lists, 2012)
Alternate Chemical Names
- ACRYLIC ACID
- ACRYLIC ACID, [WASTE]